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Technical Paper

Oxidation Catalytic Converter and Emulsified Fuel Effects on Heavy-Duty Diesel Engine Emissions

2002-03-04
2002-01-1277
A study was conducted to assess the effects of a water-diesel fuel emulsion with and without an oxidation catalytic converter (OCC) on steady-state heavy-duty diesel engine emissions. Two OCCs with different metal loading levels were used in this study. A 1988 Cummins L10-300 heavy-duty diesel engine was operated at the rated speed of 1900 rpm and at 75% and 25% load conditions (EPA modes 9 and 11 respectively) of the 13 mode steady-state test as well as at idle. Raw exhaust emissions' measurements included total hydrocarbons (HC), oxides of nitrogen (NOx) and nitric oxide (NO). Diluted exhaust measurements included total particulate matter (TPM) and its primary constituents, the soluble organic (SOF), sulfate (SO42-) and the carbonaceous solids (SOL) fractions. Vapor phase organic compounds (XOC) were also analyzed. The SOF and XOC samples were analyzed for selected polynuclear aromatic hydrocarbons (PAHs).
Technical Paper

Nonuniformity and NO2/NOx Ratio Effects on the SCR Performance under Transient Engine Conditions

2014-04-01
2014-01-1556
Selective catalytic reduction (SCR) systems are in use on heavy duty diesel engines for NOx control. An SCR NOx reduction efficiency of higher than 95% is required to meet the proposed increasingly stringent NOx emission standards and the 2014-2018 fuel consumption regulations. The complex engine exhaust conditions including the nonuniformity of temperature, flow, and maldistribution of NH3 present at the catalyst inlet need to be considered for improved performance of the SCR system. These factors cause the SCR to underperform negatively impacting the NOx reduction efficiency as well as the NH3 slip. In this study, the effects of the nonuniformity of temperature, flow velocity and maldistribution of NH3 on the SCR performance were investigated using 1-dimensional (1D) model simulations for a Cu-zeolite SCR. The model was previously calibrated and validated to reactor and steady-state and transient engine experimental data.
Technical Paper

Modeling and Numerical Simulation of Diesel Particulate Trap Performance During Loading and Regeneration

2002-03-04
2002-01-1019
A 2-dimensional numerical model (MTU-FILTER) for a single channel of a honeycomb ceramic diesel particulate trap has been developed. The mathematical modeling of the filtration, flow, heat transfer and regeneration behavior of the particulate trap is described. Numerical results for the pressure drop and particulate mass were compared with existing experimental results. Parametric studies of the diesel particulate trap were carried out. The effects of trap size and inlet temperature on the trap performance are studied using the trap model. An approximate 2-dimensional analytical solution to the simplified Navier-Stokes equations was used to calculate the velocity field of the exhaust flow in the inlet and outlet channels. Assuming a similarity velocity profile in the channels, the 2-dimensional Navier-Stokes equations are approximated by 1-dimenisonal conservation equations, which is similar to those first developed by Bissett.
Technical Paper

Modeling Study of Active Regeneration of a Catalyzed Particulate Filter Using One-Dimensional DOC and CPF Models

2011-04-12
2011-01-1242
The catalyzed particulate filter (CPF), used in conjunction with a diesel oxidation catalyst (DOC) is an important aftertreatment device used to meet Environmental Protection Agency (EPA) heavy-duty diesel emission standards for particulate matter (PM). Numerical modeling of these exhaust after-treatment devices decreases the time and cost of development involved. Modeling CPF active regeneration gives insight into the PM oxidation kinetics, which helps in reducing the regeneration fuel penalty. As seen from experimental data, active regeneration of the CPF results in a significant temperature increase into the CPF (up to 8°C/sec) which affects the oxidation rate of particulate matter (PM). PM oxidation during active regeneration was determined to be a function of filter PM loading, inlet temperature and inlet hydrocarbon concentration.
Journal Article

Model-Based Estimation and Control System Development in a Urea-SCR Aftertreatment System

2008-04-14
2008-01-1324
In this paper, a model-based linear estimator and a non-linear control law for an Fe-zeolite urea-selective catalytic reduction (SCR) catalyst for heavy duty diesel engine applications is presented. The novel aspect of this work is that the relevant species, NO, NO2 and NH3 are estimated and controlled independently. The ability to target NH3 slip is important not only to minimize urea consumption, but also to reduce this unregulated emission. Being able to discriminate between NO and NO2 is important for two reasons. First, recent Fe-zeolite catalyst studies suggest that NOx reduction is highly favored by the NO 2 based reactions. Second, NO2 is more toxic than NO to both the environment and human health. The estimator and control law are based on a 4-state model of the urea-SCR plant. A linearized version of the model is used for state estimation while the full nonlinear model is used for control design.
Technical Paper

Extended Kalman Filter to Estimate NO, NO2, Hydrocarbon and Temperatures in a DOC during Active Regeneration and Under Steady State Conditions

2015-04-14
2015-01-1059
Diesel Oxidation Catalysts (DOC) are used on heavy duty diesel engine applications and experience large internal temperature variations from 150 to 600°C. The DOC oxidizes the CO and HC in the exhaust to CO2 and H2O and oxidizes NO to NO2. The oxidation reactions are functions of its internal temperatures. Hence, accurate estimation of internal temperatures is important both for onboard diagnostic and aftertreatment closed loop control strategies. This paper focuses on the development of a reduced order model and an Extended Kalman Filter (EKF) state estimator for a DOC. The reduced order model simulation results are compared to experimental data. This is important since the reduced order model is used in the EKF estimator to predict the CO, NO, NO2 and HC concentrations in the DOC and at the outlet. The estimator was exercised using transient drive cycle engine data. The closed loop EKF improves the temperature estimate inside the DOC compared to the open loop estimator.
Technical Paper

Extended Kalman Filter Estimator for NH3 Storage, NO, NO2 and NH3 Estimation in a SCR

2013-04-08
2013-01-1581
This paper focuses on the development of an Extended Kalman Filter for estimating internal species concentration and storage states of an SCR using NOX and NH₃ sensors. The motivation for this work was twofold. First, knowledge of internal states may be useful for onboard diagnostic strategy development. In particular, significant errors between the outlet NOX or NH₃ sensors, reconstructed from estimated states, and the measured NOX or NH₃ concentrations may aid OBD strategies that attempt to identify particular system failure modes. Second, the EKF described estimates not only stored ammonia but also NO, NO₂ and NH₃ gas concentrations within and exiting the SCR. Exploiting knowledge of the individual species concentrations, instead of lumping them together as NOX, can yield improved closed loop urea controller performance in terms of reduced urea consumption and better NOX conversion.
Technical Paper

Experimental and Modeling Results Comparing Two Diesel Oxidation Catalyst - Catalyzed Particulate Filter Systems

2008-04-14
2008-01-0484
Steady-state particulate loading experiments were conducted on an advanced production catalyzed particulate filter (CPF), both with and without a diesel oxidation catalyst (DOC). A heavy-duty diesel engine was used for this study with the experiments conducted at 20, 40, 60 and 75 % of full load (1120 Nm) at rated speed (2100 rpm). The data obtained from these experiments were used and are necessary for calibrating the MTU 1-D 2-Layer CPF model. These experimental and modeling results were compared to previous research conducted at MTU that used the same engine but an earlier development version of the combination of DOC and CPF. The motivation for the comparison of the two systems was to determine whether the reformulated production catalysts performed as good or better than the early development catalysts. The results were compared to understand the filtration and oxidation differences between the two DOC+CPF and the CPF-only aftertreatment systems.
Technical Paper

Experimental Study Comparing Particle Size and Mass Concentration Data for a Cracked and Un-Cracked Diesel Particulate Filter

2009-04-20
2009-01-0629
Steady state loading characterization experiments were conducted at three different engine load conditions and rated speed on the cracked catalyzed particulate filter (CPF). The experiments were performed using a 10.8 L 2002 Cummins ISM-330 heavy duty diesel engine. The CPF underwent a ring off failure, commonly seen in particulate filters, due to high radial and axial temperature gradients. The filters were cracked during baking in an oven which was done to regenerate PM collected after every loading characterization experiment. Two different configurations i.e. with and without a diesel oxidation catalyst (DOC) upstream of the CPF were studied. The data were compared with that on an un-cracked CPF at similar engine conditions and configurations. Pressure drop, transient filtration efficiency by particle size and PM mass and gaseous emissions measurements were made during each experiment.
Technical Paper

Experimental Studies of an Advanced Ceramic Diesel Particulate Filter

2008-04-14
2008-01-0622
A Cummins ISB 5.9 liter medium-duty engine with cooled EGR has been used to study an early extrusion of an advanced ceramic uncatalyzed diesel particulate filter (DPF). Data for the advanced ceramic material (ACM) and an uncatalyzed cordierite filter of similar dimensions are presented. Pressure drop data as a function of mass loadings (0, 4, and 6 grams of particulate matter (PM) per liter of filter volume) for various flow rate/temperature combinations (0.115 - 0.187 kg/sec and 240 - 375 °C) based upon loads of 15, 25, 40 and 60% of full engine load (684 N-m) at 2300 rpm are presented. The data obtained from these experiments were used to calibrate the MTU 1-D 2-Layer computer model developed previously at MTU. Clean wall permeability determined from the model calibration for the ACM was 5.0e-13 m2 as compared to 3.0e-13 m2 for cordierite.
Technical Paper

Emissions and Fuel Usage by the U. S. Truck and Bus Population and Strategies for Achieving Reductions

1974-02-01
740537
This paper presents an approach to modeling the United States truck and bus population. A detailed model is developed that utilizes domestic factory sales figures combined with a scrappage factor as a building block for the total population. Comparison with historical data for 1958-1970 shows that the model follows trends well for intermediate parameters such as total vehicle miles per year, total fuel consumption, scrappage, etc. Fuel consumption and HC, CO, NO2, CO2 and particulate matter emissions for gasoline and diesel engines are of primary interest. The model details these parameters for the time span 1958-2000 in one-year increments. For HC and CO, truck and bus emissions could equal or exceed automobile emissions in the early 1980s, depending on the degree of control. Three population control strategies are analyzed to determine their effects on reducing fuel consumption or air pollution in later years.
Technical Paper

Effects of an Oxidation Catalytic Converter on Regulated and Unregulated Diesel Emissions

1994-03-01
940243
In this study, the effects of an oxidation catalytic converter (OCC) on regulated and unregulated emissions from a 1991 prototype Cummins I.10-310 diesel engine fueled with a 0.01 weight percent sulfur fuel were investigated. The OCC's effects were determined by measuring and comparing selected raw exhaust emissions with and without the platinum-based OCC installed in the exhaust system, with the engine operated at three steady-state modes. It was found that the OCC had no significant effect on oxides of nitrogen (NOX) and nitric oxide (NO) at any mode, but reduced hydrocarbon (HC) emmissions by 60 to 70 percent. The OCC reduced total particulate matter (TPM) levels by 27 to 54 percent, primarily resulting from 53 to 71 percent reductions of the soluble organic fraction (SOF). The OCC increased sulfate (SO42-) levels at two of the three modes (modes 9 and 10), but the overall SO42- contribution to TPM was less than 6 percent at all modes due to the low sulfur level of the fuel.
Technical Paper

Effects of a Catalyzed Particulate Filter on Emissions from a Diesel Engine: Chemical Characterization Data and Particulate Emissions Measured with Thermal Optical and Gravimetric Methods

2003-03-03
2003-01-0049
A wide range of emissions were characterized from a heavy-duty diesel engine operated on conventional low sulfur (∼375 ppm) fuel, equipped with manually controlled EGR and a catalyzed particulate filter (CPF). The effect of the CPF and engine load was studied, along with a comparison of results between the gravimetric and thermal optical methods (TOM) for determining diesel particulate levels. Data were obtained from four of the EPA old 13 mode test cycle steady-state operating conditions, i.e., Modes 11, 10, 9, and 8 using a 1995 Cummins M11-330E engine with a Corning EX-80 cordierite particulate filter, coated with a platinum catalyst (5 g/ft3).
Journal Article

Effects of Biodiesel Blends on Particulate Matter Oxidation in a Catalyzed Particulate Filter during Active Regeneration

2010-04-12
2010-01-0557
Active regeneration experiments were performed on a production diesel aftertreatment system containing a diesel oxidation catalyst and catalyzed particulate filter (CPF) using blends of soy-based biodiesel. The effects of biodiesel on particulate matter oxidation rates in the filter were explored. These experiments are a continuation of the work performed by Chilumukuru et al., in SAE Technical Paper No. 2009-01-1474, which studied the active regeneration characteristics of the same aftertreatment system using ultra-low sulfur diesel fuel. Experiments were conducted using a 10.8 L 2002 Cummins ISM heavy-duty diesel engine. Particulate matter loading of the filter was performed at the rated engine speed of 2100 rpm and 20% of the full engine load of 1120 Nm. At this engine speed and load the passive oxidation rate is low. The 17 L CPF was loaded to a particulate matter level of 2.2 g/L.
Technical Paper

Development of the Methodology for Quantifying the 3D PM Distribution in a Catalyzed Particulate Filter with a Terahertz Wave Scanner

2014-04-01
2014-01-1573
Optimizing the performance of the aftertreatment system used on heavy duty diesel engines requires a thorough understanding of the operational characteristics of the individual components. Within this, understanding the performance of the catalyzed particulate filter (CPF), and the development of an accurate CPF model, requires knowledge of the particulate matter (PM) distribution throughout the substrate. Experimental measurements of the PM distribution provide the detailed interactions of PM loading, passive oxidation, and active regeneration. Recently, a terahertz wave scanner has been developed that can non-destructively measure the three dimensional (3D) PM distribution. To enable quantitative comparisons of the PM distributions collected under different operational conditions, it is beneficial if the results can be discussed in terms of the axial, radial, and angular directions.
Technical Paper

Development of a 1-D Catalyzed Diesel Particulate Filter Model for Simulation of the Oxidation of Particulate Matter and Gaseous Species During Passive Oxidation and Active Regeneration

2013-04-08
2013-01-1574
Numerical modeling of aftertreatment systems has been proven to reduce development time as well as to facilitate understanding of the internal physical and chemical processes occurring during different operating conditions. Such a numerical model for a catalyzed diesel particulate filter (CPF) was developed in this research work which has been improved from an existing numerical model briefly described in reference. The focus of this CPF model was to predict the effect of the catalyst on the gaseous species concentrations and to develop particulate matter (PM) filtration and oxidation models for the PM cake layer and substrate wall so as to develop an overall model that accurately predicts the pressure drop and PM oxidized during passive oxidation and active regeneration. Descriptions of the governing equations and corresponding numerical methods used with relevant boundary conditions are presented.
Technical Paper

Development of a 1-D CPF Model to Simulate Active Regeneration of a Diesel Particulate Filter

2009-04-20
2009-01-1283
A quasi-steady 1-dimensional computer model of a catalyzed particulate filter (CPF) capable of simulating active regeneration of the CPF via diesel fuel injection upstream of a diesel oxidation catalyst (DOC) or other means to increase the exhaust gas temperature has been developed. This model is capable of predicting gaseous species concentrations (HC's, CO, NO and NO2) and exhaust gas temperatures within and after the CPF, for given input values of gaseous species and PM concentrations before the CPF and other inlet variables such as time-varying temperature of the exhaust gas at the inlet of the CPF and volumetric flow rate of exhaust gas.
Technical Paper

Design and Computer Simulation of Microprocessor Controlled Lubricating Oil Cooling System for Truck Diesel Engine

1988-02-01
880488
A microprocessor controlled lubricating oil cooling system of truck diesel engine was designed to minimize the sump oil temperature fluctuation during start-up and nonsteady engine operations. Model reference adaptive control method is utilized in the control system design. The analysis involved in the design of the microprocessor controlled oil cooling system, and the applications of a special vehicle-engine-cooling system (VEC) computer simulation code in the implementation and testing of the model reference adaptive control strategy are described. Using the VEC simulation code, the performance of the microprocessor controlled oil cooling system and the conventionally controlled oil cooling systems were compared for the ATB, temperature disturbances, and cold weather transient tests. An explanation of each test, as well as a review of the results of comparison tests are presented.
Technical Paper

Ceramic Particulate Traps for Diesel Emissions Control - Effects of a Manganese-Copper Fuel Additive

1988-02-01
880009
The effect of the use of a manganese-copper fuel additive with a Corning EX-47 particulate trap on heavy-duty diesel emissions has been investigated; reductions in total particulate matter (70%), sulfates (65%), and the soluble organic fraction (SOF) (62%) were measured in the diluted (15:1) exhaust and solids were reduced by 94% as measured in the raw exhaust. The use of the additive plus the trap had the same effect on gaseous emissions (hydrocarbons and oxides of nitrogen) as did the trap alone. The use of the additive without the trap had no effect on measured gaseous emissions, although sulfate increased by 20%. Approximately 50% of the metals added to the fuel were calculated to be retained in the engine system. The metals emitted by the engine were collected very efficiently (>97%) by the trap even during regeneration, which occured 180°C lower when the additive was used.
Technical Paper

Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-04-16
2012-01-0837
A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO₂ oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.
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